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Tohoku Univ. Technology:Recovery of recycled nickel:T25-067

Selective electrodeposition of high-purity nickel from nickel-cobalt mixed aqueous solutions using general-purpose electrodes, without solvent extraction

 Nickel and cobalt demand is surging for lithium-ion battery cathode materials, driving the need for efficient separation and refining technologies. Due to their similar metallic and ionic properties, making separation challenging, the current mainstream approach relies on solvent extraction exploiting differences in complex formation behavior. However, this method involves multiple steps, uses environmentally burdensome organic solvents, and requires additional refining, such as electrowinning, to isolate the metals in pure form.  This invention provides a low-cost, low‑environmental‑impact method for selectively electrowinning nickel from nickel–cobalt mixed aqueous solutions, characterized by a simple electrolytic process using general‑purpose electrodes. In the examples, electrodeposited nickel with a purity of over 99.4% was obtained.

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